| 铂氢化物trans-[PtH(tu)(PPh3)2]Cl(tu)(THF)2(tu=SC(NH2)2)的结构 |
| STRUCTURE OF PLATINUM HYDRIDE trans-[PtH(tu)(PPh3)2]Cl(tu)(THF)2 (tu = thiourea) |
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| 摘要: 制得含硫脲配体的铂氢化物单晶trans-[PtH(tu)(PPh3)2]Cl(tu)(THF)2,其结构测定结果为:C46H55N4O2P2S2ClPt M=1052.6,单斜晶系,空间群为 P21/c,a=12.103(1),b=21.619(3),c=20.189(4)Å,β=103.31(0)°,V=5140(2)Å3,Z=4,Dc=1.360g·cm-3,F(000)=2128,R=0.050,Rw=0.063.Pt(Ⅱ)与两个磷、一个硫脲分子的硫和一个氢相配合,形成四边形配位。 |
| 关键词: 铂氢化物 硫脲 晶体结构 |
| 基金项目: |
| Abstract: The platinum hydride containing thiourea ligand trans-[PtH(tu)(PPh3)2]Cl(tu)(THF)2 has been prepared, and its structure has been determined by single crystal diffractometer. In the complex Pt(Ⅱ) is coordinated by two P, one S and one H. The presence of hydride hydrogen has been demonstrated by IR, MS and NMR. |
| Keywords: platinum hydride thiourea crystal structure |
| 投稿时间：1990-01-20 |
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| 魏春红,程国宝,郭和夫,吴锵金,施剑秋.铂氢化物trans-[PtH(tu)(PPh3)2]Cl(tu)(THF)2(tu=SC(NH2)2)的结构[J].无机化学学报,1992,8(2):187-189. |
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