| 固相配位化学反应研究——ⅩⅩⅩⅤ 热分解合成Co-N2配合物及其加氢性质研究 |
| STUDIES ON SOLID STATE REACTION OF COORDINATION COMPOUNDS XXXV. SYNTHESIS AND HYDROGENATION OF COBALT -DINITROGEN COMPLEX BY THERMODECOMPOSITION REACTION |
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| 摘要: |
| 关键词: 分子氮配合物 热分解 |
| 基金项目: |
| Abstract: This paper reports the thermodecomposition of K3[Co(CN)5N3]·2H2O both in helium and hydrogen atmosphere with gas chromatography. The product in helium at 250℃ have been studied by IR, Raman, ESR and XRD. The dinitrogen complexes of K3Co(CN)5N2 and K6[Co2(CN)10N2] have been identified, and those dinitrogen complexes could be hydrogenized under hydrogen atmosphere to obtain ammonia. |
| Keywords: thermodecomposition dinitrogen complex |
| 投稿时间：1989-10-14 |
| 摘要点击次数: 1327 |
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| 忻飞波,郑丽敏,忻新泉.固相配位化学反应研究——ⅩⅩⅩⅤ 热分解合成Co-N2配合物及其加氢性质研究[J].无机化学学报,1992,8(1):82-84. |
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