线性变位极谱法研究——Ⅻ.CAEM过程二次导数配位吸附不可逆波理论及其验证 |
INVESTIGATIONS ON POLAROGRAPHY WITH LINEARLYCHANGING POTENTIAL Ⅻ ON THE THEORY FOR THE SECOND DERIVATIVE ADSORPTIVE-COMPLEX IRREVERSIBLE WAVE WITH CAEM MECHANISM |
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摘要: 本文提出了CAEM过程线性变位二次导数极谱配位吸附不可逆波理论,并以铜(Ⅱ)-L-组氨酸—氢氧化钠体系进行验证,理论与实验结果相一致. |
关键词: 极谱 二次导数配位吸附波 |
基金项目: 国家自然科学基金资助项目 |
Abstract: In this paper, the theory .of the second derivative adsorplivc-complex wave with CAEM mechanism is described. Experiments were carried out on JP-2 type oscillopolarograph. The theoretical conclusions arc in good agrccmnt with experimental data for the reduction of Cu(Ⅱ)in 0.2mol·dm-3 NaOH-0.001mol·dm-3 L-histidinc solution. |
Keywords: polarography second derivatlve adsorptlve-complex wave |
投稿时间:1989-03-14 |
摘要点击次数: 1726 |
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吴志斌,张祖训.线性变位极谱法研究——Ⅻ.CAEM过程二次导数配位吸附不可逆波理论及其验证[J].无机化学学报,1991,7(3):363-365. |
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