| 六水合硝酸钆(Ⅲ)的晶体结构 |
| CRYSTAL STRUCTURE OF GADOLINIUM(Ⅲ)NITRATE HEXAHYDRATE |
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| 摘要: 文献已报道六水合硝酸镧的晶体结构,配位数为11,并认为六水合硝酸铈与其共结构[1];六水合硝酸镨、钕、钆的晶体结构为[RE(H2O)4(NO3)3]·2H2O(RE=Pr,Nd,Y),配位数是10.而重镧系硝酸盐水合物的结构未见文献报道.本文报道六水合硝酸钆的晶体结构.实验部分 |
| 关键词: 晶体结构 X射线衍射 配合物 六水合硝酸钆 |
| 基金项目: 国家自然科学基金委资助课题 |
| Abstract: The preparation and crystal structure of title compound arc reported. The structural determination was carried out on a RASA-IIS(RIGAKU)diffratomctcr with X-ray intensity data collected in 3°<20<52° . The space group is P1 with a=6.712(3)Å,b=9.110(6)Å ,c=11.607(8)Å, α=70.17(5)° ,β=88.80(5)° ,γ=69.04(5)° ,Z=2. the structure was solved by Patterson method and refined with a full matrix least-squares procedure to R=0.076. Each Gd(Ⅲ)ion is coordinated with ten oxygen atoms from three nitrate groups and four water molcculers, forming a distorted icosahcdron. |
| Keywords: crystal structure X-ray diffraction complex gadolinium nitrate hexahydrate |
| 投稿时间：1988-11-17 |
| 摘要点击次数: 1383 |
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| 马怀让,高胜利,杨祖培.六水合硝酸钆(Ⅲ)的晶体结构[J].无机化学学报,1991,7(3):351-353. |
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