| Zn-CCl2F2-H2O体系的低温基质隔离化学反应 |
| MI CHEMICAL REACTION IN THE SYSTEM OF Zn, F12 AND H2O AT 14K |
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| 摘要: 低温基质隔离技术与各种光谱技术相结合,作为研究活性分子、分子结构、催化、光化学和制备新物质的一种重要方法,在国外已相当普遍,特别是在无机低温制备方面,由于涉及金属原子的低温化学反应具有简单性和自发性两大优点,近十多年来已有很大发展,专家们预言,低温无机合成化学,二十年后将成为一种重要的合成方法.目前国内尚未见有报道,本文介绍我们在这方面的初步尝试. |
| 关键词: 基质隔离 低温化学 金属蒸气合成 锌 |
| 基金项目: 国家自然科学基金资助项目 |
| Abstract: We have studied the matrix isolation(MI)chemical reaction in the system of Zn, F12 and H2O at low temperature, using noble gas argon as a solid matrix. The cryogenic apparatus is a G-M refrigerator, which can reach a temperature of 14K. The sample is prepared by co-condensation method and monitored by a infrared spectrometer. From the observations, it is sure that the reaction in the system have taken place, we suggest that the products are F2C=O:Zn and ZnCl2. |
| Keywords: matrix isolation cryochemistry metal vapour synthesis zlnc |
| 投稿时间：1988-10-25 |
| 摘要点击次数: 1434 |
| 全文下载次数: 1543 |
| 王守文,古正,刘维铭,马洪,陈琪,郝身建.Zn-CCl2F2-H2O体系的低温基质隔离化学反应[J].无机化学学报,1991,7(3):349-350. |
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