高压下配合物反应动力学
UNDER HIGH PRESSURE KINETICS OF COORDINATION COMPOUNDS
作者单位
管荫桐  
摘要: 综述了高压下溶液中化学反应的活化体积△V的定义和测定方法,以及作为配合物取代反应、异构化反应、电子转移反应和光化学反应机理的判据。
关键词: 高压  活化体积  配合物反应动力学
基金项目: 
Abstract: Under high pressure definition and measurement of volume of activation for chemical reactions in solutions are reviewed. The volumes of activation may be used to diagnose the mechanisms of substitution reactions and isomerization reactions and electron transfer reactions and photochemical reactions of coordination compounds.
Keywords: high pressure  volume of activation  kinetics of complex reaction
投稿时间:1988-10-15 
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管荫桐.高压下配合物反应动力学[J].无机化学学报,1990,6(4):477-481.
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