高压下配合物反应动力学 |
UNDER HIGH PRESSURE KINETICS OF COORDINATION COMPOUNDS |
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摘要: 综述了高压下溶液中化学反应的活化体积△V≠的定义和测定方法,以及作为配合物取代反应、异构化反应、电子转移反应和光化学反应机理的判据。 |
关键词: 高压 活化体积 配合物反应动力学 |
基金项目: |
Abstract: Under high pressure definition and measurement of volume of activation for chemical reactions in solutions are reviewed. The volumes of activation may be used to diagnose the mechanisms of substitution reactions and isomerization reactions and electron transfer reactions and photochemical reactions of coordination compounds. |
Keywords: high pressure volume of activation kinetics of complex reaction |
投稿时间:1988-10-15 |
摘要点击次数: 1196 |
全文下载次数: 1711 |
管荫桐.高压下配合物反应动力学[J].无机化学学报,1990,6(4):477-481. |
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