| 希土D—葡萄糖酸配合物的红外和拉曼光谱及结构的研究 |
| IR AND RAMAN SPECTRUM STUDIES ON THE STRUCTURES OF D-GLUCURONIC ACID COMPLEXES WITH RARE EARTH IONS |
|
| 摘要: 十五种希土D-葡萄糖酸配合物的红外和拉曼光谱非常相似,结构类同,配合物的糖酸谱带明显展宽,羧酸根的对称和反对称振动谱带相差200cm-1,与希土离子单齿配位,糖酸为β构型,吡喃环上的O1和O5也参予配位,希土离子配位数是9。 |
| 关键词: 希土 葡萄糖酸结构 配合物 红外光谱 拉曼光谱 |
| 基金项目: 国家自然科学基金 |
| Abstract: The structures of fifteen RE D-glucuronate complexes were characterized by IR and Raman spectroscopy. All of them are isomorphs. The band assignments were also given out. The spectra indicated that D-glucuronic acid anions were β-anomer and were coordinated to RE ions through atom O6,O5 and O1 in the complexes. Because Ca2+ favors to coordinate to the α-anomer, RE ions may be a biology antagonism in the interacting with sugar compounds. |
| Keywords: rare earth complex D-glucuronate structure IR and Raman spectroscopy |
| 投稿时间：1988-04-27 |
| 摘要点击次数: 1382 |
| 全文下载次数: 1502 |
| 张树功,倪嘉缵.希土D—葡萄糖酸配合物的红外和拉曼光谱及结构的研究[J].无机化学学报,1990,6(4):422-426. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
