| 二(β-二酮)氧钒(Ⅳ)与含氮碱加合物的合成和表征 |
| SYNTHESIS AND CHARACTERIZATION FOR ADDUCTS OF BIS (β-DIKETONATO) OXOVANADIUM(IV) WITH NITROGEN BASES |
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| 摘要: 合成了一系列VO(β-dik)2L类型加合物,其中β-dik分别为苯甲酰丙酮,2-噻吩甲酰三氟丙酮,L3-甲基吡啶、4-甲基吡啶、吗啉、异喹啉,VO(bza)2Mor、VO(tta)2Mor、VO(tta)2iso-q为首次合成,并通过元素分析、摩尔电导、红外光谱、电子光谱、顺磁共振波谱等对加合物进行了较系统的表征工作。 |
| 关键词: 氧钒(Ⅳ) β-二酮 加合物 |
| 基金项目: 中科院科学基金 |
| Abstract: A series of adducts of the type VO(β-dik)2L, where β-dik = benzoylacetonate anion(bza), thenoyltrifluoroacetonate anion(tta), L = pyridine (py), 3-methylpyridine(3MP), 4-methylpyridine(4MP), morpholine(Mor), iso-quinoline(iso-q), have been prepared, while VO(bza)2Mor, VO(tta)2Mor, VO(tta)2iso-q were first synthesized. All adducts were character-ized by elemental analysis, molar conductivity, IR,UV and ESRspetra. |
| Keywords: oxovanadium(IV) β-diketone adducts |
| 投稿时间：1988-02-03 |
| 摘要点击次数: 1708 |
| 全文下载次数: 1736 |
| 诸葛卸梅,陈克,陶伟林.二(β-二酮)氧钒(Ⅳ)与含氮碱加合物的合成和表征[J].无机化学学报,1990,6(3):273-277. |
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