| 铁羰基化合物的研究(η5-C5H5)Fe(CO)2CH2COOR的合成 |
| STUDY ON CARBONYL COMPOUNDS OF IRON SYNTHESES OF (η5-C5H5)Fe(CO)2CH2COOR |
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| 摘要: 在我们实验室里采用环戊二烯基羰基铁的钠盐[(η5-C5H5)Fe(CO)2]Na和氯代乙酸酯ClCH2COOR(R=C2H5,C3H7,C4H9,C5H11)直接反应合成了铁羰基化合物(η5-C5H5)Fe(CO)2CH2COOR(Ⅰ). |
| 关键词: 铁羰基化合物 η5-环戊二烯基(2-烷氧基-2-氧代乙基)二羰基合铁 合成 |
| 基金项目: |
| Abstract: The reaction of sodium salt of dicarbonyl cyclopentadienyl iron, [(η5-C5H5)Fe(CO)2]Na, with chloroacetates C1CH2COOR (R = C2H5, C3H7, C4H9, C5H11) has been studied and the structures of reaction products [(η5-C5H5)Fe(CO)2]CH2COOR were determined by the analysis' of IR, 1H NMR, 13C NMR,and MS. |
| Keywords: iron carbonyl compound η5-cyclopentadlenyl(2-alkoxy-2-oxoethyl)-dicarbonyliron synthesis |
| 投稿时间：1988-07-04 |
| 摘要点击次数: 1439 |
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| 张才芬,贺灿欣,汤杰,贝浼智,曹秀峰.铁羰基化合物的研究(η5-C5H5)Fe(CO)2CH2COOR的合成[J].无机化学学报,1990,6(2):232-234. |
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