咪唑桥异多核配合物的合成和表征 |
SYNTHESIS AND CHARACTERIZATIONOF IMIDAZOLATE BRIDGED HETEROPOLYNUCLEAR COMPLEXES |
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摘要: 本文报道了六种含ida,edma及dien的Cu-Im-Co,Cu-Im-Pt,Co-Im-Cu-Im-Co和Co-Im-Zn-Im-Co异双核,异三核配合物的合成与表征。用1H NMR及反射光谱证实配合物中咪唑桥的存在,并对配合物中Cu的空间构型及成键性质进行了讨论。 |
关键词: 咪唑桥异多核配合物 铜 锌 |
基金项目: |
Abstract: Six new heteropolynuclear complexes containing tridentate ligand, ida and edma, were synthesized and characterized. The imidazolate bridges in the title complexes were ascertained by NMR and reflectance spectroscopies.The configuration and bonding character of the complexes are discussed. |
Keywords: imidazolate bridged beteropolymuclear complexes copper zime |
投稿时间:1988-10-06 |
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刘之俊,陈东,唐雯霞.咪唑桥异多核配合物的合成和表征[J].无机化学学报,1990,6(2):198-203. |
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