| 希土硼氢化物的研究 Ⅹ.含[B10H9NH2COCH=CH2]-的双苯甲酰丙酮缩1,3-丙二胺希土(Ⅲ)配合物的研究 |
| STUDIES ON RARE EARTH-HYDROBORON COMPOUNDS X.RESEARCHES ON BISBENZOYLACETONEPROPYLENEDIIMINE RARE EARTH(III) COMPLEXES CONTAINING [B10H9NH2COCH =CH2]- |
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| 摘要: 将闭式+氢+硼酸阴离子酰胺衍生物[B10H9NH2COCH=CH2]-、双苯甲酰丙酮缩1,3-丙二胺C6H5C(OH)=CHC(CH3)=N(CH3)CH=C(OH)C6H5(Bapn)及希土氯化物在丙酮-乙醇混合溶剂中进行反应,得到分子式为Ln(Bapn)3[B10H9NH2COCH=CH2]3(Ln=La,Nd,Sm,Eu,Gd,Dy)的混式配体希土配合物。通过元素分析、IR、1H NMR及摩尔电导率的测定对配合物进行了表征,还通过DTA-TG方法研究了它们的热性质。 |
| 关键词: 希土配合物 闭式烷阴离子 酰胺衍生物 |
| 基金项目: |
| Abstract: 6 new mixed ligand complexes Ln(Bapn)3(B10H9NH2COCH = CH2)3 (Bapn = bisbenzoylacetonepropylenediimine,Ln = La, Nd,Sm,Eu,Gd,Dy) have been synthesized by the reaction among (C2H5)4NB10H9NH2COCH = CH2, Bapn and LnCl3 in acetone-ethanol media and are characterized by elemental analysis, IR,1H NMR and molar conductance. The thermal properties of the complexes are investigated by DTA-TG. |
| Keywords: rare earth complex closo-hydroborate amion amide derivative |
| 投稿时间：1988-01-03 |
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| 胡培植,张伦,刘洋,张国敏.希土硼氢化物的研究 Ⅹ.含[B10H9NH2COCH=CH2]-的双苯甲酰丙酮缩1,3-丙二胺希土(Ⅲ)配合物的研究[J].无机化学学报,1990,6(2):130-135. |
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