| DTA研究二水二草酸合铬酸钾的顺、反异构化 |
| INVESTIGATION OF ISOMERIZATION BETWEEN CIS- AND TRANS-POTASSIUM DIAQUOBIS (OXALATO) CHROMATE (ⅡI) BY DTA |
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| 摘要: 顺-反异构体的研究,在配合物化学中占有重要的地位。二水二草酸合铬酸钾这一配合物顺、反异构体的制备和异构化现象的研究已有报导,但多限于水溶液体系。 |
| 关键词: 差热分析 异构化作用 构型转变热 |
| 基金项目: |
| Abstract: The isomerization betweem cis- and trans- K[Cr(C2O4)2·(H2O)2] has been studied using differential thermal analysis. The transformation of the isomerization between cis-and trans-complexes has been carried out up to 230℃ in an atmosphere of air. The heat of the transformation is ～102kJ·mol-1. |
| Keywords: differemtial thermal analysis iaomerization heat of isomer's transformation |
| 投稿时间：1988-01-25 |
| 摘要点击次数: 1941 |
| 全文下载次数: 2445 |
| 冯增媛,潘云祥.DTA研究二水二草酸合铬酸钾的顺、反异构化[J].无机化学学报,1990,6(1):99-101. |
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