| Ni[(C6H11O)2PS2]2与氮碱加合反应的研究 |
| STUDY OF ADDUCTIVE REACTION OF Ni[(C6H11O)2PS2]2 WITH NITROGEN BASES |
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| 摘要: 用光谱法研究了Ni[(C6H11O)2PS2]2与咪唑,4-甲基吡啶,2,4-二甲基吡啶,2,2'-联吡啶,乙胺,正丙胺,正丁胺和二乙胺的加合反应,测定了加合反应的平衡常数。平衡常数随着氮碱分子碱度增加而增大,随着氮碱分子空间位阻的增加而减小。讨论了几类氮碱加合反应平衡常数测定的处理方法。 |
| 关键词: 二硫代磷酸酯合镍 加合反应 平衡常数 |
| 基金项目: |
| Abstract: Reactions and the additive equilibrium constants of Ni[(C6H11O)2PS2]2 with imidazole, 4-methylpyridine, 2,4-dimethylpyridine, 2,2'-bipyridine, ethylamine, n-propylamine, n-butylamme and diethylamine have been studied spectrophotometrically. The constants increase with basicity of nitrogen base and decrease with increasing steric hindrancr of nitrogen base. Variations of the calculated constants for additive reaction of nitrogen base have been discussed. |
| Keywords: dialkyldithiophosphato nickel adductive reaction eqilibrium constant |
| 投稿时间：1988-04-23 |
| 摘要点击次数: 2065 |
| 全文下载次数: 1707 |
| 徐正,林建华,于秀华,游效曾,俞运鹏.Ni[(C6H11O)2PS2]2与氮碱加合反应的研究[J].无机化学学报,1990,6(1):25-30. |
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