| 铽、铕-邻啡啰啉-芳香化合物三元配合物的合成和性质研究 |
| STUDIES OF SYNTHESIS AND CHARACTERIZATION OF TERNARY COMPLEXES FOR Tb,Eu WITH 1,10-PHENANTHROLINE AND AROMATIC LIGANDS |
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| 摘要: 本文对Ln(phen)(C6H5COO)3、Ln(phen)2P-(OC6H4CHO)3·3H2O.Ln(phen)2P-(OC6H4COOC2H5)3(Ln=Tb、Eu)固体配合物的制备和光谱性质进行了研究。根据元素分析、红外光谱、摩尔电导测定,X射线粉末衍射、热重差热分析以及紫外可见光谱确定了其组成及配位形式,并对其发光性能进行了研究。 |
| 关键词: 希土 邻啡啰啉 苯甲酸 对羟基苯甲醛 对羟基苯甲酸乙酯 三元配合物 |
| 基金项目: |
| Abstract: In this paper,the synthesis and spectral properties of Tb(Eu) (phen)(C6H5COO)3,Tb(Eu)(phen)2(OC6H4CHO)3·3H2O,Tb(Eu)(phen)2(OC6H4COOC2H5)3 were reported. Their composition were confirmed by elementary analysis. Their solubility molar conductance,thermogravimetric analysis,differential thermal analysis were also determined.They were characterized by X-ray powder diffraction,infrared,UVand fluoreccnt spectra analysis. |
| Keywords: rare earth 1,10-phenanthroline benzoic acid p-hydroxybenzaldehyde ethyl p-hydroxybenzoate ternary coordination compound |
| 投稿时间：1987-11-30 |
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| 李林书,杨燕生.铽、铕-邻啡啰啉-芳香化合物三元配合物的合成和性质研究[J].无机化学学报,1989,5(4):84-87. |
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