| 钼铜硫异核双金属配合物的合成与结构特征的研究 |
| STUDIES ON SYNTHESIS AND STRUCTURE CHARACTERIZATION OF MOLYBDENUM-COPPER-SULFUR HETERONUCLEAR BIMETALLIC COMPLEXES |
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| 摘要: 利用新方法合成了一类新型的钼铜硫异校双金属配合物Mo(t-BuNC)4(μ-t-BuS)2CuX,3X=Cl,4X=Br,5X=I,其中3和5为未知的新化合物;研究了它们的IR,1H NMR特征;考察了它们与生体内钼铜对抗作用的可能关系。 |
| 关键词: 钼铜硫配合物 合成 结构 |
| 基金项目: 中国科学院科学基金资助的课题 |
| Abstract: In this communication we have reported ths synthesis and structure characterization ofmolybdenum-copper-sulfur heteronuclcar bimetallic complexes Me(t-BuNC)4(μ-t-BuS)2CuX,3X = Cl,4X = Br and 5X = I which were obtained by the reactions of Mo(t-BuNC)4(t-BuS)2with Cu2X2(X-Cl,Br,I). It has been studied IR and 1H NMRspectra of the complexes and examinated the possible relationship between the new Mo-Cu-S reactions and antagonistic function of molybdenum against copper in ruminants. |
| Keywords: Mo-Cu-S complex synthesis structure |
| 投稿时间：1987-10-26 |
| 摘要点击次数: 1352 |
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| 石有茂,陆世维,郭和夫.钼铜硫异核双金属配合物的合成与结构特征的研究[J].无机化学学报,1989,5(2):126-128. |
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