| S-(1-二茂铁烷基)硫代乙醇酸与胺的反应——一类新型二茂铁衍生物的合成与性质研究 |
| REACTIONS OF S-(1-FERROCENYLALKYL) THIO-GLYCOLIC ACIDS WITH AMINES-STUDIES ON SYNTHESES AND PROPERTIES OF A NOVEL TYPE OF FERROCENYL DERIVATIVES |
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| 摘要: Ratajczak等研究了S-(1-二茂铁烷基)疏代乙醇酸的合成与反应Ugi等将它们与羟胺反应,合成了一种有用的手性模板试剂。最近,Czech等用键合载体液相色谱对它们进行了光学拆分研究。本文报导了此类化合物与胺的反应,合成了一类新的化合物-S-(1-二茂铁烷基)硫代乙醇酸胺。 |
| 关键词: 二茂铁 硫代乙醇酸 胺 反应 胺盐 |
| 基金项目: |
| Abstract: This article reported reactions of S-(1-ferrocenylalkyl)thioglycolic acids and amines. Some novel type of ferrocenyl derivatives-alkyl ammonium S-(1-ferrocenylalkyl) thioglycolic were synthesized and characterized by elemental analyses.IR and H NMR spectroscopy. Their molar conductance ratios were measured,and some influences of kinds of amines were discussed. |
| Keywords: ferrocene thioglycolic acid amine reaction ammonlnm salt |
| 投稿时间：1987-10-26 |
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| 王冀英,向进福.S-(1-二茂铁烷基)硫代乙醇酸与胺的反应——一类新型二茂铁衍生物的合成与性质研究[J].无机化学学报,1989,5(2):121-125. |
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