| 环状双(环戊二烯基)钛、双(甲基环戊二烯基)钛芳氧基衍生物的合成 |
| SYNTHESIS OF CYCLIC BIS(CYCLOPENTADIENYL) TITANIUM AND BIS(METHYLCYCLOPENTADIENYL) TITANIUM AROMATOXIDE DERIVATIVES |
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| 摘要: 在氨基钠存在下,二氯二茂钛或二氯二(甲基环戊二烯基)钛分别与2,2′—二羟基联苯、1,1′—二羟基—2,2′—联萘或间苯二酚等摩尔量反应,得到了四种新的环状有机钛芳氧基衍生物。而间苯二酚与二氯二(甲基环戊二烯基)钛反应,只得到单取代产物。新合成的衍生物都经元素分析、红外、核磁鉴定。 |
| 关键词: 双(环戊二烯基)钛 双(甲基环戊二烯基)钛 芳氧基衍生物 |
| 基金项目: |
| Abstract: A series of cyclic bis(cyclopentadienyl)titanium and bis(methylcyclopentadienyl)titanium aromatoxide derivatives have been synthesized by the reaction of Cp2TiQ2or (MeCp)2TiCl2 with 2,2'-dihydrobiphenyl,1,1'-dihydro-2,2'-binaphthyl or resorcinol in 1:1 molar ratio refluxing in benzene and in the presence of sodamide.When resorcin reacted with (MeCp)2TiCl2,the product was mono-substituted instead of six-membered ring compound. The new derivatives have been characterized on the basis of their elemental analysis and spectral(IR and 1H NMR) studies. |
| Keywords: bis(cyclopentadlenyI)titanium(Ⅳ) bis(methylcyclopentadienyl)titanium(Ⅳ) aromatoxlde derivative |
| 投稿时间：1987-09-30 |
| 摘要点击次数: 1547 |
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| 申华峰,尹荣鋆.环状双(环戊二烯基)钛、双(甲基环戊二烯基)钛芳氧基衍生物的合成[J].无机化学学报,1989,5(2):117-120. |
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