| 氯仿溶剂中二氯化钯(Ⅱ)、二正辛基亚砜平衡体系的研究 |
| STUDY OF THE PALLADIUM(Ⅱ) CHLORIDE-DIOCTYL SULFOXIDE EQUILIBRIUM SYSTEM IN CHLOROFORM |
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| 摘要: 本文通过紫外光谱法及萃取研究,讨论了二氯二正辛基亚砜合钯(Ⅱ)配合物[Pd(DOSO)2Cl2]在氯仿溶剂中的离解平衡: Pd(DOSO)2Cl2⇔Pd(DOSO)Cl2+DOSO Pd(DOSO)Cl2⇔PdCl2+DOSO 并测定了25℃时的离解常数K1=(2.0±0.3)×10-3,K2=(1.3±0.1)×10-4. |
| 关键词: 钯(Ⅱ) 二正辛基亚砜 平衡体系 |
| 基金项目: |
| Abstract: The dissociation equilibrium of Pd(DOSO)2Cl2(DOSO=di-n-Octyl sulfoxide) in chloroform was studied by UV-spectrometry and extraction:Pd(DOSO)2Cl2=Pd(DOSO)Cl2+DOSOPd(DOSO)Cl2=PdCl2+DOSO The following dissociation constants were obtained at 25℃:K1=(2.0±0.3)×10-3,K2=(1.3±0.1)×10-4. |
| Keywords: palladium(Ⅱ) di-n-octyl sulfoxide equilibrium system |
| 投稿时间：1987-09-19 |
| 摘要点击次数: 1175 |
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| 戴洁,王汉章,王恤民.氯仿溶剂中二氯化钯(Ⅱ)、二正辛基亚砜平衡体系的研究[J].无机化学学报,1989,5(2):107-111. |
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