| 腙类配位化合物的研究——Ⅰ.乙酰基一和1,1′—二乙酰基二茂铁苯甲酰腙及其过渡金属螯合物的制备和性质 |
| COORDINATION COMPOUNDS OF HYDRAZONES——Ⅰ. PREPARATION AND PROPERTIES OF CHELATES OF ACETYL-AND 1,1'-DIACETYLFERROCENE AROYLHYDRAZONES WITH TRANSITION METALS |
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| 摘要: 制备了两个二茂铁基芳酰基腙:乙酰基二茂铁苯甲酰腙,FeCMe=NNHCOC6H5(HLⅠ)和1,1′--二乙酰基二茂铁苯甲酰腙,Fe(C5H4CMe=NNHCOC6H5)2(H2LⅡ)。HLⅠ和H2LⅡ与过渡金屑醋酸盐反应,得到两种螯合物:ML2Ⅰ和MLⅡ[M=Co(Ⅱ)、Zn(Ⅱ)和Cd(Ⅱ)]。对这些螯合物的元素分析,差热热重分析、IR、UV及1HNMR谱进行了详细讨论。 |
| 关键词: 二茂铁 腙 过渡金属螯合物 制备 |
| 基金项目: |
| Abstract: Two ferrocenyl aroyl hydrazones: acetylferrocene benzoylhydrazone,FeCMe = NNHCOPh(HLⅠ);1,1'-diacetylferrocene benzoylhydrazone,Fe(C5H4CMe =NNHCOPh)2(H2LⅡ)and their chelates with M(OAc)2·nH2O(M = Co,Zn and Cd) havebeen prepared. The elemental analysis,IR,UV,PMR and TG-DTA are discussed in detail and showed that these ligands are coordinated in the enolic form with transition metal acetates. |
| Keywords: ferrocene hydrazone transition metal chelate preparation |
| 投稿时间：1987-08-11 |
| 摘要点击次数: 1809 |
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| 赵刚,马永祥.腙类配位化合物的研究——Ⅰ.乙酰基一和1,1′—二乙酰基二茂铁苯甲酰腙及其过渡金属螯合物的制备和性质[J].无机化学学报,1989,5(2):22-29. |
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