| 摘要: 合成了金(Ⅲ)与七种中性氧配体RnXO(R=辛基或苯基;X=N,P,As和S;n=2,3)形成的十种配合物,可概括为两种类型:H(RnXO)x·AuCl4·Sy(RnXO=TONO、TOPO、TPPO、DOSO、DPSO、TPAsO和bipyO2;S=乙醇或水;x=1,2,3,y=0,1,2或3)和[Au(L)X2](L=bipyO2 |
| Abstract: Ten complexes of tetrachloroauric acid hydrate or their alkali salts with the series of neutral oxo compounds RnXO(R = octyl or phenyl, X = N,P,As or S,n = 2 or 3) have been synthesized and characterized by elemental analyses, molar conductance, infrared, ultraviolet and NMR spec-troscopies, and thermogravimetric techniques. The results show that the complexes are well defined complexes of the two types. H(RaXO)x·AuCl4·Sy(RaXO = TONO, TOPO, DOSO, DPSO, TPPO, TPAsO and bipyO2,S = ethanol or water, x = 1,2 or 3,y = 0,1,2 or 3) and CAu(L)(Hal)2]Hal (L = bipyO2, Hal = Cl or Br). The possible complexes structures are discussed too. |
