| 固相配位化学反应研究——ⅩⅩⅥ.(NH4)2WS4与(n-Bu)4NBr固相成簇反应 |
| STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS——XXⅥ. STUDIES ON SOLID STATE REACTIONS OF (NH4)2WS4 WITH (n-Bu)4NBr FOR PRODUCING CLUSTERS |
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| 摘要: 本文研究了(NH4)2WS4与(n-Bu)4NBr固相合成原子簇化合物的方法。指出在不同温度、不同气氛中反应生成的产物不同,并用EXAFS方法测定了[(n-Bu)4N]2W4S12簇合物的结构参数。 |
| 关键词: 相反应 配位化学 钨硫状化合物 EXAFS方法 |
| 基金项目: 联合国教科文组织资助项目;国家自然科学基金资助项目 |
| Abstract: The solid state reactions of (NH4)2WS4 with (n-Bu)4NBr for producing clusters have been studied.Three compounds, ((n-Bu)4N)2((S2)WO(μ-S)2WO(μ-S)2WS2)(Ⅰ), ((n-Bu)4N)2((S2)WS(μ-S)2WS(μ-S)2WS2)(Ⅱ), ((n-Bu)4N)2(S2W(μ-S)ⅡWS(μ-S)2WS2(μ- S)ⅡWS2)(Ⅲ) were prepared by controllingr eaction condition.The compounds were chara-ccterized by infrared spectra and electronic spectra.Using EXAFS, structural parameters of the compound(Ⅲ) was determined. |
| Keywords: solid state reaction coordination compound W-S cluster EXAFS |
| 投稿时间：1987-04-30 |
| 摘要点击次数: 2005 |
| 全文下载次数: 1990 |
| 朱慧珍,丛蓉娟,忻新泉,戴安邦,段永恒,马礼敦.固相配位化学反应研究——ⅩⅩⅥ.(NH4)2WS4与(n-Bu)4NBr固相成簇反应[J].无机化学学报,1988,4(3):1-5. |
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