| 氯化血红素/热解石墨电极对单加氧酶的模拟——Ⅱ.苯在氯化血红素/热解石墨电极上的电催化羟基化作用 |
| MODELLING MONOOXYGENASE ON HAEMA- TIN HYDROCHLORIDE/PYROLYTIC GRAPHITE ELECTRODES——Ⅱ . Electrocatalytic Hydroxylation of Benzene on Haematin Hydrochloride/Pyrolytic Graphite Electrodes |
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| 摘要: 实验结果支持了血红素(Ha.)的单体(monomer)吸附态对分子氧起电催化还原作用的观点[1];并表明,H2O2的电催化还原主要是在Ha.的二聚体(dimer)吸附态上进行。Ha./电极对苯一步羟基化生成苯酚有电催化作用。 |
| 关键词: 电催化 血红素 羟基化 苯 氧气 过氧化氢 |
| 基金项目: |
| Abstract: Experimental results indicate that monomer and dimer adsorbed species of Ha. electrocatalyse the reduction of O2 and H2O2, respectively. Electrocatalytic hydroxylation of benzene can occur on Ha./electrodes. |
| Keywords: electrocatalysis haematin hydrochloride hydroxylation benzene dioxygen hydroperoxide |
| 投稿时间：1987-03-14 |
| 摘要点击次数: 1534 |
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| 张兆龙,王仲权.氯化血红素/热解石墨电极对单加氧酶的模拟——Ⅱ.苯在氯化血红素/热解石墨电极上的电催化羟基化作用[J].无机化学学报,1988,4(2):110-113. |
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