| 含茂钛低聚物的制备与光谱 |
| PREPARATION AND SPECTRA OF TITANOCENE- CONTAINING LOW POLYMERS |
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| 摘要: 文中报道两种新的含茂钛低钛物Cp2Ti(Cl)-O-[-Ti(Cp)(O2CCH4CH-O)-O-]n-H(Ⅰ)与Cp2Ti(Cl)-O-[-Ti(Cp)(O2CCH2C10H7)-O-]u-H(Ⅰ)的制备并用元素分析和光谱(IR,1H NMR,MS)对它们进行了鉴定。 |
| 关键词: 茂钛 低聚物 光谱 |
| 基金项目: |
| Abstract: New polymers Cp2Ti(Cl)-O-C-Ti(Cp)(O2CC6H4CH3-o)-O]n-H (Ⅰ) and Cp2Ti(Cl)-O-[-Ti(Cp)(O2CCH2C10H7)-O-]nH (Ⅱ) were obtained by reacting Cp2TiCl2 with o-CH3C6H4CO2Na and C10H7CO2Na-α in benzene, respectively. They were characterized by elemental analysis and spectra (IR, 1H NMR and MS). The results were consistent with the proposed compositions, i.e. n = 2 for (Ⅰ), n = 1 or 2 for (Ⅱ). |
| Keywords: tilanocene low-polymer spectrum |
| 投稿时间：1987-01-06 |
| 摘要点击次数: 1813 |
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| 党轶.含茂钛低聚物的制备与光谱[J].无机化学学报,1988,4(1):94-96. |
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