| 镥单酞菁和镥双酞菁电子转移过程的研究 |
| INVESTIGATION OF ELECTRON TRANSFER PROCESSES ON LUTETIUM MONOPHTHALOCYANINE AND LUTETIUM DIPHTHALOCYANINE |
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| 摘要: 本文用循环伏安法研究镥单酞菁和镥双酞菁在非水溶剂中的电化学行为,获得了相应的氧化还原反应半波电位E1/2,测定了其中四个氧化还原反应的电子转移速度常数ks.指出非水溶剂对镥单酞菁和镥双酞菁的电化学行为具有程度不同的影响. |
| 关键词: 希土酞菁 电子转移 |
| 基金项目: |
| Abstract: Electrochemical behaviors for the lutetium monophthalocyanine(Lu-PcAc2H)and lutetium diphthalocyanine(LuPc2H)in non-aqueous solvents were studied with cyclic voltammetry. The half-wave potentials(E1/2)of the reclox reactions and the electron transfer rate constants(ks)for the four of these redox reactions were measured. It was shown that effects of non-aqueous solvents on electrochemical properties of LuPcAc2H were different from those of LuPc2H. |
| Keywords: lutetium monophthalocyanine lutetium diphthalocyanine electron transfer |
| 投稿时间：1986-03-11 |
| 摘要点击次数: 1803 |
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| 尹绍明,朱天培,倪嘉缵.镥单酞菁和镥双酞菁电子转移过程的研究[J].无机化学学报,1987,3(3):16-22. |
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