| 铜(Ⅱ)离子影响下酚醚的裂解 |
| CLEAVAGE OF PHENOLIC ETHER UNDER INFLUENCE OF Cu(I)ION |
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| 摘要: 4-氯-2-(对-硝基苯甲氧基)-1,3-苯二甲醛和邻-氨基苯酚生成的双Schiff碱在乙醇溶液中和水合醋酸铜反应,在Cu(Ⅱ)离子的影响下醚链裂解,生成双核配合物和对-硝基苄醇. |
| 关键词: 裂解 酚醚 双Schiff碱 Cu(Ⅱ)双核配合物 |
| 基金项目: |
| Abstract: The bis-Schiff base prepared from 4-chloro-2-(p-nitro-benzyloxy)isophthalaldehyde and o-aminophenol was treated with cupric acetate monohydrate in absolute alcohol. The ether linkage was cleaved under the influence of Cu(Ⅱ)ion and the products isolated were a copper(Ⅱ)binuclear complex and p-nitrobenzyl alcohol. |
| Keywords: cleavage phenolic ether bis-Schiff base copper(Ⅱ)binuclear coordination compound |
| 投稿时间：1986-06-27 |
| 摘要点击次数: 1483 |
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| 胡跃飞,许红,胡宏纹.铜(Ⅱ)离子影响下酚醚的裂解[J].无机化学学报,1987,3(2):91-95. |
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