| 若干镍(Ⅱ)、铜(Ⅱ)的平面型配合物对丙烯氧化反应的催化作用 |
| CATALYSIS OF OXIDATION OF PROPENE BY SOME MONO- AND BINUCLEAR POLYKETONE COMPLEXES OF NICKEL(Ⅱ)AND COPPER(Ⅱ) |
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| 摘要: 本文报道若干平面四方多酮配合物对丙烯氧化反应的催化作用.指出Ni(Ⅱ)平面四方配合物可以利用其轴向的配位空穴活化烯键. |
| 关键词: 催化 丙烯 丙酮 气相色谱 |
| 基金项目: |
| Abstract: The catalytic oxidation of propene by several square planar polyke-tone complexes was studied.It was pointed out that some C=C bond could be activated on the axial positions of certain square planar complex of nickel(Ⅱ).For the planar complexes,the facility of electron transfer between two 4-donor chelates, where the nickel(Ⅱ)chelate was used to activate C=C bond and the copper(Ⅱ)chelate to activate O2, was closely related to the similarity of the structures of the two chelates. |
| Keywords: catalysis propene ketone gas chromatography |
| 投稿时间：1986-07-21 |
| 摘要点击次数: 1317 |
| 全文下载次数: 1416 |
| 施舒,游效曾,李培,李大光.若干镍(Ⅱ)、铜(Ⅱ)的平面型配合物对丙烯氧化反应的催化作用[J].无机化学学报,1987,3(1):104-108. |
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