| 钪、钇硝酸盐与5-Br-PADAP固体配合物的合成及性质研究 |
| SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF SCANDIUM AND YTTRIUM NITRATES WITH 5-Br-PADAP |
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| 摘要: 关于5-Br-PADAP与金属离子固态配合物的研究,迄今为止国内外未见报导。本文在丙酮中使5-Br-PADAP与硝酸钪及硝酸钇反应,制得了它们的固态配合物。 |
| 关键词: 钪 钇 苯酚 配合物 合成 |
| 基金项目: |
| Abstract: The solid complexes of scandium and yttrium nitrates with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAF) have been synthesized using acetone as reaction medium. Composition of complexes were determined by elemental analysis as following: Sc(NO3)2L·HL 1/2 H2O, Y(NO3)3·(HL)3·2H2O(HL=5-Br-PADAP)The complexes have been characterized by infrared spectra, ultraviolet-visible spectra, solubilities and molar conductances, thermogravimetric (TG) and differential thermal analyses (DTA), and X-ray powder diffraction. |
| Keywords: scandium yttrium phenol complex synthesis |
| 投稿时间：1986-01-06 |
| 摘要点击次数: 1696 |
| 全文下载次数: 1621 |
| 王桂兰,胡之德.钪、钇硝酸盐与5-Br-PADAP固体配合物的合成及性质研究[J].无机化学学报,1986,2(4):106-111. |
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