四(邻N-甲基烟酰胺基)苯卟啉与Cu(Ⅱ)的反应动力学研究 |
KINETIC STUDIES OF REACTION OF Cu(Ⅱ) WITH TETRA(O-N-METHYLNICOTINAMIDE) PHENYLPORPHYRIN |
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摘要: 在20.0±0.1℃,0.1M KCl介质及乙酸或丁二酸缓冲条件下,研究了水溶性的四(邻N—甲基烟酰胺基)苯卟啉(H2-TM(O-Nic)PP)与Cu(Ⅱ)的反应动力学。 |
关键词: 曲(邻N-甲基烟酰胺基)苯卟啉 铜 反应动力学 |
基金项目: |
Abstract: The kinetic of reaction of Cu (n) with water-soluble tetra(o-N-methyl-nicotinamide) phenylporphyrin, H2-TM(O-Nic)pp, was studied spectropho-tometrically in O.lM KC1, acetate and succinate buffer solutions at 20.0±0.1℃. The experimental results show that the rate of Cu(Ⅱ) incorporation into H2-TM(O-Nic)PP is first-order in H2-TM(O-Nic)PP. |
Keywords: tetra (O-N-methylnicotinamide) phenylporphyrin copper reaction kinetics |
投稿时间:1985-10-04 |
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李飞跃,任建国,秦子斌.四(邻N-甲基烟酰胺基)苯卟啉与Cu(Ⅱ)的反应动力学研究[J].无机化学学报,1986,2(4):41-49. |
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