| Au(HPMBP)(PMBP)3和Ti(PMBP)2(OEt)Cl螯合物的合成与性质 |
| SYNTHESIS AND CHARACTERIZATION OF Au(HPMBP)(PMBP)3 AND Ti(PMBP)2(OEt)CI CHELATES |
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| 摘要: AuCl3·HCl·4H2O和TiCl4分别与1-苯基-3-甲基-4-苯甲酰基吡唑酮-5(酮式HPMBP)的饱和乙醇溶液反应,首次合成了化学式为Au(HPMBP)(PMBP)3和Ti(PMBP)2(OEt)Cl(OEt=OC2H5-)的螯合物。用元素分析、IR、1HNMR、电导和质谱(MS)研究了它们的性质,推测出了分子结构式。 |
| 关键词: 金 钛 乙氧基(OEt) 1-苯基-3-甲基-4-苯甲酰基吡喹酮-5(HPMBP) |
| 基金项目: |
| Abstract: The chelates of he formulations AU(HPMBP)(PMBP)3 and Ti(PMBP)2 (OEt)Cl(OEt = OC22H5-)have been synthesised at first by using AuCl3·HC1·4H2O and TiCl4 with std. ethanol (EtOH) soln. of l-phenyl-3-methyl-4-benzoyl -pyrazoloas-5 (keto form HPMBP), respectively. The structure and, properties of the form chelates have been characterized by physico-chemical techniques, viz, elemental analysis, conductivity, IR, 1HNMR and mass spec-tra(MS). |
| Keywords: gold titanium 1-phenyl-3-methyl-4-beazoylpyrazoloae-5(HPMBP) ethoxy group (OEt) |
| 投稿时间：1985-10-28 |
| 摘要点击次数: 1608 |
| 全文下载次数: 1841 |
| 安兴民,贾殿赠,李勇.Au(HPMBP)(PMBP)3和Ti(PMBP)2(OEt)Cl螯合物的合成与性质[J].无机化学学报,1986,2(3):108-113. |
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