| 群链R3i-D4d-C2v及dN体系在C2v对称性场中的能量矩阵 |
| GROUP CHAIN R3i-D4d-C2v AND ENERGY MATRICES OF dN SYSTEM IN LIGAND FIELD OF C2v SYMMETRY |
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| 摘要: R3i-D4d-C2v是一条群链。本文讨论如何应用D4d群的标准基函作为C2v群的基函来写出dN体系在C2v对称性场中各配场谱项的能量矩阵H10H1中的Hel。部分完全可以应用D4d的H1中的Hel。,因而简化了计算。所得能量矩阵H1与前文列出的H1等价。 |
| 关键词: dN体系 C2v对称性 正交对称性 能量矩阵 |
| 基金项目: 中国科学院科学基金 |
| Abstract: R3i-D4d-C20 is a group chain. In this paper we use the standard basis functions of D4d group as the basis functions of C2v group to calculate the energy matrices H1 of the terms of dN system in ligand field of C2v symmetry. The Hel. part in H1 of C2v symmetry can use the He1. part in H1 of D4d symmetry and thus simplifies the calculations. Energy matrices thus obtained are equivalent to those listed in a previous paper[5]. |
| Keywords: dN system C2v symmetry orthorhombie symmetry energy matrices |
| 投稿时间：1985-07-19 |
| 摘要点击次数: 1322 |
| 全文下载次数: 1672 |
| 曾成,臧焰,王国雄.群链R3i-D4d-C2v及dN体系在C2v对称性场中的能量矩阵[J].无机化学学报,1986,2(3):23-32. |
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